Transgranular stress corrosion cracking an overview. The tensile stress is usually residual stress from welding but also can be caused by mechanical damage or cold forming. Scc is frequently observed to cause brittle behavior in otherwise ductile materials and can exhibit intergranular, transgranular, or mixed modes of crack propagation. The interaction of corrosion fatigue and stresscorrosion. In this chapter, the incidence of scc on important industrial alloys from the. In the introduction to stress corrosion cracking on canadian oil and gas pipelines the neb notes. In our previous research, the transgranular stress corrosion cracking behavior. The process of cracking is not strictly a mechanical process, as the corrosivity of the environment strongly affects the fracture mode. The texts are the property of their respective authors and we thank them for giving us the opportunity to share for free to students, teachers and users of the web their texts will used only for illustrative educational and scientific purposes only. Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking. Transgranular stress corrosion cracking of highpressure pipelines in contact with solutions of near neutral ph r. Ways of propagation of scc scc can proceed in either of two ways. Transgranular corrosion is a type of localized corrosion which occurs along cracks or faults across the crystals in metals and alloys.
A computational model for intergranular stress corrosion. When subjected to an external stress or when it is left under residual stress when in contact with certain corrosive environments many alloys will develop cracks which propergate in either intergranular or transgranular mode. Stress corrosion cracking international institute of. In alloys, the active path for preferential electrochemical attack during transgranular stress corrosion cracking is associated with a continuous plane of disordered material which is created by the motion of dislocations through a matrix of shortrange order. Intergranular stress corrosion cracking igscc of austenitic stainless steels, usually aisi 304 steel, is a serious problem in boiling water reactors bwr. Commercial titanium can suffer intergranular stresscorrosion cracking see stress corrosion cracking in methanolic environments and red fuming nitric acid but otherwise it is immune to failure. Transgranular attack has a very characteristic branching habit which is easily recognizable in scanning electron microscopy sem fractographic and metallographic section examination. Simulation of inter and transgranular crack propagation. Susceptible alloy tensile stress residual or applied scc can proceed in either of two ways. This paper reports that the results indicate that the mechanisms of intergranular stress corrosion cracking and transgranular stress corrosion cracking of cu30 au are identical. It is as a result of chromium depletion, mainly due to the precipitation of chromium carbides in the grain boundaries.
Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. Highpurity copper is immune to stress corrosion cracking in most. Stress corrosion cracking scc is a well know phenomena in conventional uhsss such as ph 174 and ph 188 46. Stress corrosion cracking odonnell consulting engineers. Is the transgranular stress corrosion cracking is because of chlorides present in the. Intergranular stress corrosion cracking transgranular stress corrosion cracking 14. In general, however, all susceptible alloys are unstable in the environment concerned but are largely protected by a surface film. Many alloys, notably the austenitic stainless steels, exhibit intergranular as well as transgranular stress corrosion cracking scc in ct environments. Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack. A computational model for intergranular stress corrosion cracking thesis by juli an j. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. The mechanism of cracking in both these modes and the conditions under which the transi. Both intergranular ig and transgranular tg scc in uhsss has been attributed to. Stress corrosion cracking of carbon steel in ethanol.
Delanty introduction the majority of instances of stress corrosion cracking scc in highpressure gas pipelines has been associated with the propagation of intergranular cracks. Stress corrosion cracking in pipelines sciencedirect. An additional document titled addendum on circumferential scc was published in 1998 that specifically addressed the much lesscommon circumferential scc. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Characterization of the fracture surface was made using sem and semeds. Intergranular stress corrosion cracking scc was produced in ethanolgasoline blend with 15. Stress corrosion cracking can be either transgranular or intergranular. Intergranular scc the cracks which propagate along the grain boundaries called as intergranular stress corrosion cracking as shown in the following figures. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. The exact degree to which any of these alloys is resistant to any form of corrosion or stress corrosion depends upon its composition, microstructure, and the exact nature of the solution and solution temperature to which it is exposed.
Transgranular stress corrosion cracking of highpressure. Stress corrosion cracking scc is an environmentallydriven failure mechanism that can be found in metal alloys of all types including pure metals. Welded steel pipelines that are used to transport oil and gas under high pressure have been known to fail by stress corrosion cracking scc, and the. The results indicate that the electrochemical contribution to the scc of cu30au in 0. Scc requires a tensile stress and a corrosive environment. Both intergranular and transgranular stress corrosion cracking is. Chloride is the leading cause of transgranular cracking.
There appears to be no unique mechanism of transgranular stress corrosion cracking, since no single factor is common to all susceptible alloys. Stress corrosion cracking scc is a result of synergic interaction of mechanical tension and chemical reaction. This is, of course, a very complex question for a forum like this. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Susceptibility to stress corrosion cracking of 254smo ss. Transgranular stress corrosion cracking tgscc is the same as igscc, but. Sulfide stress cracking ssc cracking usually is designated as either intergranular intercrystalline or transgranular transcrystalline.
Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Stress corrosion of austenitic steels is usually transgranular. Both intergranular and transgranular stress corrosion cracking are. The alloy composition and structure influence the scc susceptibility 14. Intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. Intergranular stress corrosion cracking igscc is stress corrosion cracking where the grain boundaries of a susceptible material are cracked due to stress and an agressive environment. Stress corrosion cracking can proceed in one of two ways. In the presence of tensile stress, cracking may occur along grain boundaries and this type of corrosion is frequently called intergranular stress corrosion cracking igscc or simply intergranular corrosion cracking. Stress corrosion cracking starts from corrosion sites at the material surfaces and progresses into a brittle manner. It is associated with the simultaneous presence of a number of factors. Transgranular stress corrosion cracking occurs mainly in chloride cracking of austenitic steels. This post will cover essential information about two forms of corrosion chosen by me, that are intergranular corrosion and stress corrosion. If the sample was simultaneously stressed and dealloyed, the fracture mode was transgranular cleavage. Alloy b2 is damaged by intergranular stress corrosion cracking in the heat affected region when subjected to organic solvents comprising of sulfuric acid at 120oc.
What is intergranular stress corrosion cracking igscc. Crack growth is driven by the inelastic deformation at the sharp crack tip. Mechanistic differences in transgranular and intergranular. Intergranular stress corrosion cracking of welded steel twi.
Pdf modeling of inter and transgranular stress corrosion crack. Intergranular corrosion facts and how to reduce the risk. Intergranular stress corrosion cracking igscc is defined as cracking that occurs along the grain boundaries of crystallites due to corrosion. Intergranular stress corrosion cracking of copper in. Characterization of intergranular stress corrosion. At the micro level, through the grain as transgranular cracks crack extension along the grain boundaries as intergranular cracks map crack, when the stress corrosion. Internal stress corrosion cracking of shale gas flowlines. Stress corrosion cracking behavior of nickel base alloys.
This led to the stress value of stress corrosion cracking, corrosion medium than there is no need of material stress fracture is much smaller. When alloyed with oxygen or aluminum, transgranular stresscorrosion cracking can be induced in laboratory tests in seawater and. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. This type of failure is known as stress corrosion cracking, often abbreviated to scc. Why is chloride stress corrosion cracking transgranular. Stress corrosion cracking scc is a very common cause of failures for the.
At low values of stress, failure occurred by brittle intergranular cracking, and at high values of stress, failure occurred by brittle transgranular cracking. This form of corrosion cracking is caused by a combination of tensile stresses on the material in the presence of corrosive conditions. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. Intergranular and transgranular stress corrosion cracking of cu 30au. However, the stress corrosion cracking scc of 304 stainless. Intergranular corrosion what is intergranular corrosion. Some studies reported that stress corrosion cracking scc in. Nickel alloys, stainless steels ss, aluminum alloys and other metallic alloys are susceptible to scc. Stress corrosion cracking scc is the cracking induced from the combined influence. Introduction crystal plasticity is now classically used in material science to capture. Intergranular stress corrosion cracking scc of pipelines has been known to cause pipeline failure since the 1960s and is associated with a high ph, above 9, in the electrolyte in direct contact with the external pipe surface. The mechanism of stress corrosion cracking scc of cu30au in 0. Observations of intergranular stress corrosion cracking in.
R moli in partial ful llment of the requirements for the degree of doctor of philosophy california institute of technology pasadena, california 2009 defended may 5, 2009. Both of type 304 and type 316 stainless steels showed quite similar. Stress corrosion cracking scc of magnesium mg alloys. Scc can be transgranular or intergranular and is found over a limited potential range in environments that promote passive behavior of the. Cepa stress corrosion cracking recommended practices 2nd edition. Characterization of intergranular stress corrosion cracking of 304. Transgranular cracking is a key characteristic of chloride induced stress corrosion cracking in austenitic stainless steels. It follows the pattern of grains in the individual lattices of the material. Dislocation substructure vs transgranular stress corrosion. Duplex stainless steels possess superior resistance to both transgranular and intergranular stress corrosion cracking. Intergranular cracks follow the grain boundaries in the metal. Instances of tgscc have been associated with dilute solutions with ph values in the region of 6. Intergranular and transgranular stress corrosion cracking.
Occasionally, both types of cracking are observed in a failure. Stress corrosion cracking intergranular scc of an inconel heat exchanger tube with the crack following the grain boundaries. Intergranular corrosion igc is a selective attack in the vicinity of the grain boundaries of a stainless steel. Both intergranular and transgranular stress corrosion cracking are observed. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. Intergranular stress corrosion cracking an overview. Intergranular stress corrosion cracking igscc is the progressive nucleation and growth of cracks by localized corrosion along the grain boundaries in metals in the presence of stress or strain.
Abstract many alloys, notably the austenitic stainless steels, exhibit intergranular as well as transgranular stress corrosion cracking scc in c1. Abstract many alloys, notably the austenitic stainless steels, exhibit intergranular as well as transgranular stress corrosion cracking scc in c1 environments. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Intergranular stress corrosion cracking of copper a case study. Cracks may propagate along the grain boundaries igscc intergranular stress corrosion cracking or 2. With high enough stress level the intergranular scc mechanism can change to transgranular scc cracking at the pearlite.